The condensation reactions that give rise to the highly aromatic coke product also tend to retain sulfur, nitrogen, and metals, so that the coke is enriched in these elements relative to. We would appreciate hearing from you about this document. Pdf simulation of delayed coking reaction in coke drum. This unit uses vacuum residue obtained from fractionation as the feed the main objective of this unit is to separate out middle distillates, and give products such as lpg and naphtha. The schematic flow diagram below depicts a typical delayed coker.
A study for the implementation of an economic optimization of. The effects of pressure, feed type, and temperature on product yields were analyzed. Popwasher case study use on delayed coker unit dcu martinez, ca a refinery owner needed a safer, faster, and better method to breakout their critical path dcu flanges. The objective of this paper is to compare the prediction capability of different correlations for calculating delayed coking yields. There are three types of cokers used in oil refineries. See the complete equipment and unit turndown and shutdown series of topics as part of oracle from becht, the global engineering knowledgeondemand platform for the energy, process and power industries the series including high risk, high impact concerns, symptoms and consequences to evaluate during transient operations in conjunction with expert insights. The delayed coking unit is the main converter of residue and usually a refinery that owns a coker is considered to be residual free sawarkar et al. Our delayed coker unit fractionator boot water chloride. The evaluation was developed taking operation data reported in the literature into account for delayed coking commercial plants. Therefore, brief descriptions of each of the processing steps preceding the delayed coking unit are provided below.
Analysena, mg and ca chloride in vacuum residue water 4. The fractionator tower also known as the main fractionator or combination tower receives the unit feed and the overhead hot vapors from the coking drum in the bottom tower section. Industrial mechanical equipment operation and maintenance training courses include stepbystep general procedure for installation, assembly and dismantling. Delayed coker unit pinch an article from linhoffmarch on how to do a pinch for delayed coker unit with examples and calulations. Feed to coking unit is heavy hydrocarbon from bottom of different units and also includes slop. Baytown refinery coker facility, tx hydrocarbons technology. F in a highly optimized unit design thermal cracking in the fired heater has been reported to be as low as 680.
Total investment is a primary concern for most refinery upgrade projects. Delayed coker feed originates from the crude oil supplied to the refinery. When the two processes are compared, the investment cost per barrel of installed capacity for a delayed coker is usually lower than an ebullated bed. Reference 5 presents apc implementation at a delayed coking unit in khartoum refinery. Although delayed coking is an old process, there are many challenges associated with it, especially as crude slates continue to change and greater throughput is. The return bend elbow fittings connecting adjacent tubes in a delayed coker furnace are improved by subjecting the interior surface of the fittings to a diffusion hardfacing process. Schuf valves for delayed coker systems pb1010907 revision 1.
A coker or coker unit is an oil refinery processing unit that converts the residual oil from the vacuum distillation column into low molecular weight hydrocarbon gases, naphtha, light and heavy gas oils, and petroleum coke. Manipulation of coker operations to avoid shot coke production is typically not economically advantageous for the refiner because of the resultant loss of liquid yield and coker throughput. The preowned delayed coker unit belongs to an entire package, consisting of a crude distillation unit, vacuum unit and a hydrogen production unit with psa. The delayed coker unit is basically a tertiary unit for producing value added products such as petroleum cokepetcoke. Page 1 delayed coker unit dcu introduction delayed coker unit is largestest of its type among all iocl plants in india. Schematic diagram of delayed coker unit to gascon section salient features minimization of shot coke formation by parametric and feedstock quality adjustment. Preventing emissions in coke removal digitalrefining. The process thermally cracks the long chain hydrocarbon molecules in the residual oil feed into shorter chain molecules leaving behind the excess carbon in the form of. Delayed coking was the first type of coker introduced in the refining market place. By far the largest amount of coking capacity is represented by the delayed coking process. The next generation of switch valves for delayed coker service. Hazards of delayed coker unit dcu operations showing 14 of 8 pages in this text. Mcdermott awarded epc contract for delayed coker unit for. The process itself and decoking methods can cause erosion to the tubes and especially the ubends.
The nature of the delayed coking process virtually dictates that organic fines will be present either because of 1 feedstock composition, especially in the delayed coking process or 2 coke attrition, especially in the fluid coking and flexicoking processes. Recently, a new type of morphology, called transition coke, has been described, but this morphology. Oct 29, 2015 oil refining industryenergy recovery at a delayed coker unit. Because there is so much equipment used to perform coke drum operations, to decoke the drums, and the nature of the cracked resid is to turn solid at lower temperatures and velocities, this area of the refinery stereotypically has a. In the next section figure 3 and figure 4, the temperaturepressure profile, will then be utilized to describe the basic process in an. While delayed coking is simple enough, the cyclic nature of the process. Dec 26, 2016 the delayed coker unit is basically a tertiary unit for producing value added products such as petroleum cokepetcoke. Comparison of correlations for estimating product yields. It is already known that the chemical and physical properties and composition of the feedstock and processing conditions affect coke morphology. Unit ontime capacity has been increased, contributing to the units cash flow.
Jul 09, 2010 houston, july 9, 2010 conocophillips nyse. Delayed coking is the technology most used to upgrade vacuum residue into highvalue products, but in this process, secondary reactions produce coke. Knowledge of commercial delayed coking units as well as that of the glc pilot delayed coker is used in. A delayed coker is a type of coker whose process consists of heating a residual oil feed to its thermal cracking temperature in a furnace with multiple parallel passes. Since its invention schuf has continued to develop the valve, with many innovations. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke delayed coking is one of the unit processes used in many oil refineries. Delayed coker feed material delayed coker coker feedstock is material from the refinery vacuum unit, which is otherwise used as road asphalt. The return bend elbow fittings 18 connecting straight sections 16 of adjacent tubes in a delayed coker furnace are improved by subjecting the interior surface of the fittings to a diffusion hardfacing process. The delayed coker process is a batch process, one of the most hostile environments in the refinery due to the abrasive and erosive properties of the coke byproduct and crucial to a refinerys profitability. Industrial maintenance training plant operator training.
The objective of the coker is to process the asphaltlike material to produce higher value products, such as gasoline, diesel fuel, lpg, and petroleum coke. Delayed coking process design, operations and optimization. F high temperatures will result in excessive thermal cracking and heater fouling this results in excessive amounts of gas oil being sent to the delayed coker. Wo1999060075a1 improved delayed coker unit furnace. Oil refining industryenergy recovery at a delayed coker unit. In a delayed coking process the feed is heated in a furnace to cracking temperature, typically 485505c, and it is then injected into a process. Once removed from the coke drums, the coke is transported away from the receiving area. The one that is by far the most commonly used is the delayed coker. The process configuration of a delayed coking unit resembles that of visbreaking figure 5. Research pdf available january 2014 with 412 reads.
From here, the coke is either exported from the refinery or crushed, washed, and stored prior to export. Narl fuels lp summary of environmental assessment process. Page 38 the hot product vapours from the filling drums will be routed to the coker fractionator. All equipment including the coke cutting systems have to meet these requirements. Delayed coking units fractionate the coke drum overhead products into fuel gas low molecular weight gases up. Mcdermott will provide epc for a delayed coker unit in kstovo, russia, that will process 2. Come by chance refinery delayed coker project proponent. East china university of science and technology date. The delayed coking complex will be built at the 17 milliontonyear kstovo refinery in central russias nizhny novgorod region. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke. A basic refinery flow diagram is shown on the following page in figure 1. Pdf advanced control of the delayed coking unit in. Pdf process flow determines coker heater performance.
Delayed coker operators with a pitpad system have made efforts, together with mechanical equipment suppliers, to improve the mechanical steps in the process, in particular with installation of top and bottom unheading equipment. Delayed coker unit coke drums and hydroblast systems. Reliability of the structure block equipment is covered in the delayed coker operations and reliability training, a twoday course offered at refcomm budapest. Delayed cokers generally operate to a refiners best economic advantage when processing vacuum residue from lower cost heavy crudes. The primary focus on multimedia inputs like graphics, animation and interactivity help in very clearly understanding operating working principles and maintenance procedures.
Although delayed coking is an old process, there are many challenges associated with it, especially as crude slates continue to change and greater throughput is required of delayed coking units. Delayed coker simulation and tutorial simulation gses envision simulation is a realtime dynamic process simulation program used for operator training. This part of the presentation will explore a refinerys experience with coker furnace tube thinning that was unusual compared to typical damage profile. This part of the presentation will explore a refinerys experience with coker furnace tube thinning that.
A typical schematic flow diagram of a delayed coking unit. It is based upon a rigorous and highfidelity mathematical process model to provide a realistic dynamic response of a process unit. The delayed coker furnace is the heart of the unit. Eil has experience in process design and engineering for both open art and licensed units. Pdf delayed coking units convert heavy crude oil or topping refinery. Coking process technologies available commercially differ in the type of reactor used and fall into two main categories.
The complete bidding document for above mentioned mrtender are. Title link to download bidding document bidding document. Patented innovation schuf is the inventor of the lift plug valve. In addition to the delayed coker, the complex will include a diesel hydrotreater, gas fractionation unit, sulfur and hydrogen production units, and associated systems. Thus, in the current economic environment, the coker is frequently the most important unit in the refinery. However, inorganic solids are not as typical and it is the interaction of the. Decoking, however, was still a manual job accomplished by using. Becht knowledgeondemand series turndown fired equipment pdf. The preheated feed is flown into the bottom of the reactor, an isolated. Refining community chevron coker safety and reliability. In addition to the revamp of an existing residue fluidized catalytic cracker, srip involved installation of five new units at the refinery, including an 82,000bd crude distillation unit, vacuum distillation unit, delayed coker, hydrocracker, and bitumenblowing unit.
Wo1999060075a1 pctus1999007353 us9907353w wo9960075a1 wo 1999060075 a1 wo1999060075 a1 wo 1999060075a1 us 9907353 w us9907353 w us 9907353w wo 9960075 a1 wo9960075 a1 wo 9960075a1 authority wo wipo pct prior art keywords fittings furnace delayed coker coker unit return bend prior art date 19980515 application number. A foam over in a delayed coker unit can be a costly event, not only causing loss of production but also requiring a lot of manual labour to clean coke out of the. Coke formation in coke drum of a delayed coking unit. Delayed coker free download as powerpoint presentation. Pdf advanced control of the delayed coking unit in khartoum. A pumparound heat exchange will be used to remove heat from the fractionator.
To understand the delayed coking process, one must understand how the delayed coker is integrated with the rest of the refinery. The project was initiated in november 1998 when exxon mobil awarded the contract to provide conocolicensed delayed coking technology for two of exxons refineries, to the conocobechtel coker technology alliance, a business unit of the bechtel corporation. On 29 february 2000, exxon mobil usa announced the start of construction of the new delayed coker at its existing baytown refinery. While delayed coking is simple enough, the cyclic nature of the process gives ample scope to the talents of the troubleshooter. A reference list is available upon request the first switch valve built to our design was installed in 1983. For the purpose of illustrating the operating cycles, figure 3. In one such study the source of chloride in coker distillation column was identified to be the desalter drain water containing soluble mg and ca chlorides which was added to the slop.
The heavy feed, typically from the refinerys atmospheric andor vacuum unit, is introduced into the bottom of the fractionator vessel, t1. See the complete equipment and unit turndown and shutdown series of topics as part of oracle from becht, the global engineering knowledgeondemand platform for the energy, process and power industries. Delayed coker unit dcu civil engineering ce notes edurev. This unit uses vacuum residue obtained from fractionation as the feed the main objective of this unit is to separate out middle. These include the addition of electric, hydraulic and.
Valves are cycled frequently and failure can lead to a complete shutdown of a unit, resulting in large process and financial costs. Paul of great lakes carbon corporation of port arthur, tx. Delayed coking capacity has increased greatly in recent years, mostly due to the heavier crude slates being used in refineries. The technology of choice for most of these projects has been delayed coking. Crude and vacuum distillation delayed coker fluidizedbed catalytic cracker fcc alkylation hydrotreating hydrogen plant blending delayed coker is the second unit in this sevenstep overview of refining. The proponent proposes the construction and operation of a delayed coker complex equipped with a small integrated crude oil fractionation unit, a distillate hydrotreater, and assorted utilities in come by chance, northwest of the existing refinery. Petroleum residue upgrading via delayed coking publications of. Refining delayed coker process diagram the challenges to the delayed coker process are detailed on the next page.
Delayed coker units in india delayed coker units dcus in india are built in extreme ambient. Hazards of delayed coker unit dcu operations unt digital. Work is fast and continuous, and downtime is crippling to production. Eil has already licensed five grass roots delayed coker units and. Delayed coking is one of the unit processes used in many oil.
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